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Reduction of imines with sodium borohydride


Shake at frequent intervals for four hours and allow to stand overnight.
The hydrochloride has mp 182-182.5C.Feng (103) extracted Ephedra equisetina, first with 80 alcohol and finally with.2 acetic acid.Manske Holmes, The Alkaloids, Vol III, p 343-344, Academic Press (1953), the ephedrine bases may be extracted from the plant material, following general procedures.By the reduction of ephedrine or pseudo-ephedrine, the same deoxyephedrine (methamphetamine, C10H15N is obtained (29, 39). It is also used in the second step of the oxymercuration reaction to replace mercury (Hg) with.A method of extraction has been described by Chou (165 Powdered Ma Huang was extracted with cold benzene in the presence of diluted sodium carbonate.The hydrobromide and the hydrochloride, unlike the corresponding pseudo-ephedrine salts, are very sparingly soluble in chloroform (30).The Chugaev Reaction 12 1962 Cyclobutane Derivatives from Thermal Cycloaddition Reactions 12 1962 Olefins from Amines: The Hofmann Elimination Reaction and Amine Oxide Pyrolysis 11 1960 Favorskii Rearrangement of Haloketones 11 1960 Arylation of Unsaturated Compounds by Diazonium Salts 11 1960 Demjanov and Tiffeneau-Demjanov idee cadeau ado fnac Ring.The ephedrine synthesis described by Manske and Johnson (74) and by Skita and Keil (77) in 1929 is founded on code promo alice garden avril 2018 a different reaction.The base forms white rhombic crystals, mp 118C (from water) and is much less soluble in water than ephedrine.Hydrochloride, colorless needles, mp 181-182C, the salt is soluble in chloroform.By itself, it will generally not reduce esters, carboxylic acids, or amides (although it will reduce acyl chlorides to alcohols).Dl-Ephedrine (racemic ephedrine is the synthetic, inactive ephedrine of commerce.However, ephedrine is volatile even at room temperature; a sample exposed by Read to the air showed a loss of 33 after.5 months (107).Carboxylic Acids and Derivatives, Nitrogen Compounds, and Sulfur Compounds 36 1988 Phosphorus Addition at sp2 Carbon Nitrone-Olefin Cycloaddition Reaction 36 1988 Fluorination with Diethylaminosulfur Trifluoride and Related Aminofluorosulfuranes 35 1988 Persulfate Oxidation of Phenols and Arylamines (The Elbs and the Boyland-Sims Oxidations) 35 1988 Beckmann.Ephedrine and pseudo-ephedrine are quite stable compounds.Dissolve the residue in an excess of N/10 sulphiric acid, add 20 mils of water, and titrate the excess acid with N/10 sodium hydroxide, using methyl red as indicator; each millilitre of N/10 sulphuric acid is equivalent.01651.Syntheses of homologs and isomers of ephedrine have been described by Schmidt and Calliess (25 Hyde, Browning, and Adams (281 Sanchez (282 Manske and Johnson (75 Fourneau and Barrelet (53 Fourneau, Benoit and Firmenich (54 Fréon and Ser (283 Kanao (278 Beals and Gilfillan (279.The reaction has been further elaborated by Coles, Manske, and Johnson (76 by Skita, Keil and coworkers (78, 79, 262, 263) and by Couturier (265).
The corresponding bromohydrin was reacted with methylamine; several isomeric ephedrines were obtained.


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